ArticleDalton transactions (Cambridge, England : 2003)2024
Defluorination of HFCs by a magnesium reagent.
Article in Dalton transactions (Cambridge, England : 2003), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Selective defluorination of 1,1,1,2-tetrafluoroethane by lithium phosphide reagents.Dalton transactions (Cambridge, England : 2003) · 2026Article
- Silicate-Enabled Mechanochemical Mineralization of Polymeric and Nonpolymeric PFAS into Sodium Fluoride.Journal of the American Chemical Society · 2026Article
- Chemical recycling of hydrofluorocarbons by transfer fluorination.Nature chemistry · 2026Article
- Synthetic methodologies for the chemical recycling of fluorocarbons.Nature reviews. Chemistry · 2026Review
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Reaction of a series of HFCs with a main group reagent containing a Mg-Mg bond results in defluorination to form the corresponding magnesium fluoride complex. In the case of 1,1,1,2-tetrafluoroethane (HFC-134a) generation of the fluoride occurs alongside selective formation of 1,1-difluoroethene. DFT calculations have been carried out to better understand the selectivity and compare the barriers for sp
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Registered trials
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