ArticleJournal of the American Chemical Society2024
Elucidating the Role of Reduction Kinetics in the Phase-Controlled Growth on Preformed Nanocrystal Seeds: A Case Study of Ru.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 22 citations in OpenAlex.
- Metal Atoms and Quantum Dots Coexist for Water Electrolysis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Modulating Ru-Co bond lengths in RuNature communications · 2025Article
- Enhanced p-d Orbital Coupling in Unconventional Phase RhSb Alloy Nanoflowers for Efficient Ammonia Electrosynthesis in Neutral Media.Angewandte Chemie (International ed. in English) · 2025Article
- Phase-Controlled Synthesis of Ru Supported on Carbon Nitride and the Application in Photocatalytic HMaterials (Basel, Switzerland) · 2025Article
- Facile Synthesis of Rhodium-Based Nanocrystals in a Metastable Phase and Evaluation of Their Thermal and Catalytic Properties.Small methods · 2025Article
- Unconventional Hexagonal Close-Packed High-Entropy Alloy Surfaces Synergistically Accelerate Alkaline Hydrogen Evolution.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This study demonstrates the crucial role of reduction kinetics in phase-controlled synthesis of noble-metal nanocrystals using Ru nanocrystals as a case study. We found that the reduction kinetics played a more important role than the templating effect from the preformed seed in dictating the crystal structure of the deposited overlayers despite their intertwined effects on successful epitaxial growth. By employing two different polyols, a series of Ru nanocrystals with tunable sizes of 3-7 nm and distinct patterns of crystal phase were synthesized by incorporating different types of Ru seeds. Notably, the use of ethylene glycol and triethylene glycol consistently resulted in the formation of Ru shell in natural hexagonal close-packed (
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Registered trials
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