Unified and vector theory of Raman scattering in gas-filled hollow-core fiber across temporal regimes.

Raman scattering has found renewed interest owing to the development of gas-filled hollow-core fibers, which constitute a unique platform for exploration of novel ultrafast nonlinear phenomena beyond conventional solid-core-fiber and free-space systems. Much progress has been made through models for particular interaction regimes, which are delineated by the relation of the excitation pulse duration to the time scales of the Raman response. However, current experimental settings are not limited to one regime, prompting the need for tools spanning multiple regimes. Here, we present a theoretical framework that accomplishes this goal. The theory allows us to review recent progress with a fresh perspective, makes new connections between distinct temporal regimes of Raman scattering, and reveals new degrees of freedom for controlling Raman physics. Specific topics that are addressed include transient Raman gain, the interplay of electronic and Raman nonlinearities in short-pulse propagation, and interactions of short pulses mediated by phonon waves. The theoretical model also accommodates vector effects, which have been largely neglected in prior works on Raman scattering in gases. The polarization dependence of transient Raman gain and vector effects on pulse interactions via phonon waves is investigated with the model. Throughout this Perspective, theoretical results are compared to the results of realistic numerical simulations. The numerical code that implements the new theory is freely available. We hope that the unified theoretical framework and numerical tool described here will accelerate the exploration of new Raman-scattering phenomena and enable new applications.