ArticleChemical science2024
Controllable π-π coupling of intramolecular dimer models in aggregated states.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Geometric Evolution of Perylene-Based Intermolecular π-π Dimers Toward Static and Dynamic Multicolor Emission.Angewandte Chemie (International ed. in English) · 2026Article
- Pressure-induced emission enhancement through a synergistic effect between suppression of excimer formation and activation of aggregation-induced emission.Chemical science · 2026Article
- Influence of Chlorine Substitution on the Structures and Photophysical Properties of 9,10-Distyrylanthracene (DSA).Journal of fluorescence · 2026Article
- A Perylene-Based Bright Red-Emitting Probe for Wash-Free Cell Plasma Membrane Imaging Via Excimer Formation.Journal of fluorescence · 2025Article
- Counterion-Mediated Luminophore Dimerization.Angewandte Chemie (International ed. in English) · 2025Article
- On the Potential Energy Surface of the Pyrene Dimer.International journal of molecular sciences · 2024Article
- Recent Progress in Solid-State Room Temperature Afterglow Based on Pure Organic Small Molecules.Molecules (Basel, Switzerland) · 2024Review
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
π-π coupling as a common interaction plays a key role in emissions, transport and mechanical properties of organic materials. However, the precise control of π-π coupling is still challenging owing to the possible interference from other intermolecular interactions in the aggregated state, usually resulting in uncontrollable emission properties. Herein, with the rational construction of intramolecular dimer models and crystal engineering, π-π coupling can be subtly modulated by conformation variation with balanced π-π and π-solvent interactions and visualized by green-to-blue emission switching. Moreover, it can rapidly respond to temperature, pressure and mechanical force, affording a facile way to modulate π-π coupling
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.