ArticleACS catalysis2023
A Lewis Acid-Controlled Enantiodivergent Epoxidation of Aldehydes.
Aliakbar Mohammadlou, Chetan Joshi, Brendyn P Smith, Li Zheng, Stephanie A Corio, Virginia M Canestraight, Saeedeh Torabi Kohlbouni, S Maryamdokht Taimoory, Babak Borhan, Richard Staples and 2 more
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In one paragraphArticle in ACS catalysis, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 · Who and what moneyAuthors and funding
12 authors.
Aliakbar MohammadlouDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
Chetan JoshiDepartment of Chemistry, Binghamton University, Binghamton, New York 13902, United States.
Brendyn P SmithDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
Li ZhengDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
Stephanie A CorioDepartment of Chemistry, Binghamton University, Binghamton, New York 13902, United States.
Virginia M CanestraightDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
Saeedeh Torabi KohlbouniDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
S Maryamdokht TaimooryDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States.
Babak BorhanDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.ORCID 0000-0002-3193-0732 Richard StaplesDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.ORCID 0000-0003-2760-769X Mathew J VetticattDepartment of Chemistry, Binghamton University, Binghamton, New York 13902, United States.ORCID 0000-0001-5709-0885 William D WulffDepartment of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.ORCID 0000-0002-5668-4312 Funding
Mechanistic Studies at the Frontiers of CatalysisR35GM145320 · NIGMS · STATE UNIVERSITY OF NY,BINGHAMTON · PI Mathew J Vetticatt · 2022 to 2026
$1.9MNew Chiral Br??nsted Acids for Asymmetric SynthesisR01GM094478 · NIGMS · MICHIGAN STATE UNIVERSITY · PI WULFF, WILLIAM DEAN · 2011 to 2014
$1.0MNIGMS NIH HHS R01 GM094478NIGMS NIH HHS R35 GM145320
6 · The paper itselfAbstract
Two epoxidation catalysts, one of which consists of two VANOL ligands and an aluminum and the other that consists of two VANOL ligands and a boron, were compared. Both catalysts are highly effective in the catalytic asymmetric epoxidation of a variety of aromatic and aliphatic aldehydes with diazoacetamides, giving high yields and excellent asymmetric inductions. The aluminum catalyst is effective at 0 °C and the boron catalyst at -40 °C. Although both the aluminum and boron catalysts of (
Indexed as
asymmetric catalysisDFT calculationsenantiodivergenceepoxidation
Identifiers
PMID38516048
PMCPMC10956421
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