Evidence map›Paper›PMID 38514900›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Tuning the Electronic Property of Reconstructed Atomic Ni-CuO Cluster Supported on N/O-C for Electrocatalytic Oxygen Evolution.

Xinran Li, Yang-Yi Liu, Cheng Li, Huaiguo Xue, Songqing Chen, Qiang Xu, Huan Pang

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Xinran LiSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.ORCID https://orcid.org/0000-0003-2114-8437
Yang-Yi LiuSchool of Electrical Engineering, Engineering Technology Research Center of Optoelectronic Technology Appliance, Tongling University, Tongling, Anhui, 244061, P. R. China.
Cheng LiShenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), Academy for Advanced Interdisciplinary Studies, SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL) and Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong, 518055, P. R. China.
Huaiguo XueSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
Songqing ChenSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
Qiang XuShenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), Academy for Advanced Interdisciplinary Studies, SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL) and Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong, 518055, P. R. China.
Huan PangSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.ORCID https://orcid.org/0000-0002-5319-0480

Funding

Excellent doctoral dissertation of Yangzhou UniversityNational Natural Science Foundation of China 21671170National Natural Science Foundation of China 21875207National Natural Science Foundation of China NSFC-U1904215Program for Young Changjiang Scholars of the Ministry of Education, China Q2018270Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials ZDSYS20210709112802010Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
6 · The paper itself

Abstract

Electrochemical activation usually accompanies in situ atom rearrangement forming new catalytic sites with higher activity due to reconstructed atomic clusters or amorphous phases with abundant dangling bonds, vacancies, and defects. By harnessing the pre-catalytic process of reconstruction, a multilevel structure of CuNi alloy nanoparticles encapsulated in N-doped carbon (CuNi nanoalloy@N/C) transforms into a highly active compound of Ni-doped CuO nanocluster supported on (N/O-C) co-doped C. Both the exposure of accessible active sites and the activity of individual active sites are greatly improved after the pre-catalytic reconstruction. Manipulating the Cu/Ni ratios of CuNi nanoalloy@N/C can tailor the electronic property and d-band center of the high-active compound, which greatly optimizes the energetics of oxygen evolution reaction (OER) intermediates. This interplay among Cu, Ni, C, N, and O modifies the interface, triggers the active sites, and regulates the work functions, thereby realizing a synergistic boost in OER.

Indexed as

electrocatalysisnanoalloypre‐catalystsingle atom

Identifiers

PMID38514900
PMCPMC11165517

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.