ArticleCommunications chemistry2024
Synergetic binary organocatalyzed ring opening polymerization for the precision synthesis of polysiloxanes.
Article in Communications chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 10 citations in OpenAlex.
- Study of Reaction Parameters for the Precise Synthesis of Low-Molecular-Weight Oligosiloxanes.Materials (Basel, Switzerland) · 2025Article
- Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others.Beilstein journal of nanotechnology · 2025Review
- Organomediated polymerization.Communications chemistry · 2024Article
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Authors and funding
3 authors at 2 institutions in 1 country.
Funding
Abstract
Organocatalytic ring-opening polymerization (ROP) is a versatile method for synthesizing well-defined polymers with controlled molecular weights, dispersities, and nonlinear macromolecular architectures. Despite spectacular advances in organocatalytic ROP, precision synthesis of polysiloxanes remains challenging due to the mismatch in polarity between highly polar initiators and nonpolar monomers and polymers and the difficulty in suppressing the formation of scrambling products via transetherification reactions during ROP of cyclic siloxanes. Here, we describe a binary organocatalytic ROP (BOROP) of hexamethylcyclotrisiloxane (D3) employing organic bases as catalysts and (thio)ureas as cocatalysts. The BOROP of D3 using triazabicyclodecene (TBD) and (thio)ureas generates polydimethylsiloxanes (PDMSs) with narrow dispersity (M
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Registered trials
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