ArticleNature communications2024
Structurally diverse macrocycle co-crystals for solid-state luminescence modulation.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Achiral guest-mediated modulation of circularly polarized luminescence in chiral charge-transfer cocrystals.Chemical science · 2026Article
- Inclusion co-crystals based on Tröger's base molecular box for thermally activated delayed fluorescence.Nature communications · 2026Article
- Enhanced Solid-State Luminescence of Supramolecular Tessellation Assemblies Through Förster Resonance Energy Transfer From Counterions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Explainable Machine Learning for Efficient Cocrystal Prediction: Leveraging Morgan Fingerprints to Decode Local Structure-Cocrystal Formation Relationships.The journal of physical chemistry. A · 2026Article
- Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle.Angewandte Chemie (International ed. in English) · 2026Article
- Beyond Cocrystals: Hierarchical Functional Assemblies via Noncovalent Synthesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Single-crystal growth of complex non-fullerene acceptor molecules via cocrystallization.Nature communications · 2026Article
- Engineering Supramolecular Systems with a Bis(pyridyl)azine Derivative and Different Hydrogen and Halogen Donors.Crystal growth & design · 2026Article
- Ternary Inclusion Co-Crystals for Efficient Photothermal Conversion and Solar-Driven Water Evaporation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Article
- Calix[2]azolium[2]benzimidazolone hosts for selective binding of neutral substrates in water.Nature communications · 2024Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Organic co-crystals offer an opportunity to fabricate organic functional materials. Traditional co-crystals are generally packed following the segregated or mixed stacking mode, leading to the lack of structural and functional diversity. Herein, we report three sets of macrocycle co-crystals with identical co-constitutions. The macrocycle co-crystals differ in the stoichiometric ratios (2:1, 1:1, and 2:3) of the constituents and molecular packing modes. The co-crystals are constructed using triangular pyrene-macrocycle and 1,2,4,5-tetracyanobenzene exploiting exo-wall charge-transfer interactions. Interestingly, the three co-crystals exhibit distinct, tunable emission properties. The corresponding emission peaks appear at 575, 602, and 635 nm, covering yellow via orange to red. The X-ray diffraction analyses and the density functional theory calculations reveal the superstructure-property relationships that is attributed to the formation of different ratios of charge-transfer transition states between the donor and acceptor motifs, resulting in red-shifted luminescence.
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