Pore-scale simulation of low-salinity waterflooding in mixed-wet systems: effect of corner flow, surface heterogeneity and kinetics of wettability alteration.

The initial wettability state of the candidate oil reservoirs for low-salinity waterflooding (LSWF) is commonly characterized as mixed-wet. In mixed-wet systems, both the two-phase flow dynamics and the salt transport are significantly influenced by the corner flow of the wetting phase. Thus this study aims at comprehensive evaluation of LSWF efficiency by capturing the effect of corner flow and non-uniform wettability distribution. In this regard, direct numerical simulations under capillary-dominated flow regime were performed using the OpenFOAM Computational Fluid Dynamics toolbox. The results indicate that corner flow results in the transport of low-salinity water ahead of the primary fluid front and triggers a transition in the flow regime from a piston-like to multi-directional displacement. This then makes a substantial difference of 22% in the ultimate oil recovery factors between the 2D and quasi-3D models. Furthermore, the interplay of solute transport through corners and wettability alteration kinetics can lead to a new oil trapping mechanism, not reported in the literature, that diminishes LSWF efficiency. While the findings of this study elucidate that LSWF does exhibit improved oil recovery compared to high-salinity waterflooding, the complicating phenomena in mixed-wet systems can significantly affect the efficiency of this method and make it less successful.