Evidence map›Paper›PMID 38499604›Full record

ArticleNature communications2024

Encoding ordered structural complexity to covalent organic frameworks.

Lei Wei, Xinyue Hai, Tongtong Xu, Zidi Wang, Wentao Jiang, Shan Jiang, Qisheng Wang, Yue-Biao Zhang, Yingbo Zhao

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Dynamic covalent organic frameworks.Chemical science · 2026
    Review
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Lei Wei *School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.
Xinyue Hai *School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.
Tongtong XuSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.
Zidi WangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.
Wentao JiangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.
Shan JiangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China.ORCID http://orcid.org/0000-0002-3990-8687
Qisheng WangShanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201210, China.ORCID http://orcid.org/0000-0002-0614-6903
Yue-Biao ZhangSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China. zhangyb@shanghaitech.edu.cn.ORCID http://orcid.org/0000-0002-8270-1067
Yingbo ZhaoSchool of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, P. R. China. zhaoyb2@shanghaitech.edu.cn.ORCID http://orcid.org/0000-0002-6289-7015

Funding

Science and Technology Commission of Shanghai Municipality (Shanghai Municipal Science and Technology Commission) 22QC1401500
6 · The paper itself

Abstract

Installing different chemical entities onto crystalline frameworks with well-defined spatial distributions represents a viable approach to achieve ordered and complex synthetic materials. Herein, a covalent organic framework (COF-305) is constructed from tetrakis(4-aminophenyl)methane and 2,3-dimethoxyterephthalaldehyde, which has the largest unit cell and asymmetric unit among known COFs. The ordered complexity of COF-305 is embodied by nine different stereoisomers of its constituents showing specific sequences on topologically equivalent sites, which can be attributed to its building blocks deviating from their intrinsically preferred simple packing geometries in their molecular crystals to adapt to the framework formation. The insight provided by COF-305 supplements the principle of covalent reticular design from the perspective of non-covalent interactions and opens opportunities for pursuing complex chemical sequences in molecular frameworks.

Identifiers

PMID38499604
PMCPMC10948875

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.