ArticleBiomacromolecules2024
Covalent Adaptable Networks with Tailorable Material Properties Based on Divanillin Polyimines.
Article in Biomacromolecules, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Effects of Isohexide Stereochemistry on Vinylogous Urethane Covalent Adaptable Networks.Macromolecules · 2025Article
- Mechanochemical Synthesis of Recyclable Biohybrid Polymer Networks Using Whole Biomass.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
2 authors.
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Abstract
Covalent adaptable networks (CANs) are being developed as future replacements for thermosets as they can retain the high mechanical and chemical robustness inherent to thermosets but also integrate the possibility of reprocessing after material use. Here, covalent adaptable polyimine-based networks were designed with methoxy and allyloxy-substituted divanillin as a core component together with long flexible aliphatic fatty acid-based amines and a short rigid chain triamine, yielding CANs with a high renewable content. The designed series of CANs with reversible imine functionality allowed for fast stress relaxation and tailorability of the thermomechanical properties, as a result of the ratio between long flexible and short rigid amines, with tensile strength (σ
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