ArticleNature communications2024
Tailoring d-band center of high-valent metal-oxo species for pollutant removal via complete polymerization.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
47 citing papers in PubMed.
- Tailoring High-Valent Iron-Oxo Species Redox via Extended π-Fe3d-O2p Orbital Overlapping Toward Chemical-Efficient Water Purification.Angewandte Chemie (International ed. in English) · 2026Article
- Proton-gated multisite concerted proton-electron transfer-like pathway in a dual-atom framework for selective water purification.Nature communications · 2026Article
- Near-infrared-active Nd-BiONature communications · 2026Article
- Selective Two-Electron Phenol Oxidation Polymerization for Water Purification.Angewandte Chemie (International ed. in English) · 2026Article
- Beyond radicals: harnessing non-radical pathways in MOF-based functional materials for water purification.Chemical science · 2026Review
- A complementary descriptor for elucidating selective PMS activation by iron single-atom catalysts with tunable interatomic distances.Science advances · 2026Article
- Overcoming catalyst deactivation with in-situ electrochemical regeneration in packed-bed reactors enabling long-lived wastewater purification.Nature communications · 2026Article
- In Situ Turning Pollutants Into Catalysts: A Phase-Transition Self-Catalysis Paradigm for Sustainable Water Treatment.Angewandte Chemie (International ed. in English) · 2026Article
- Upcycling Water Pollutants Into Long-Chain Polymers via Synergistic Interfacial Dechlorination and Organic Radical Stabilization.Angewandte Chemie (International ed. in English) · 2026Article
- Interfacial and Kinetic Limitations in Alkaline OER: A Case Study of Electronic Modifications Using Fe in CuO Lattice.Small methods · 2026Article
- Tailoring d-p orbital hybridization of single-atom Cu-NNature communications · 2026Article
- Stiff interlocked nanoclay aerogels for synergistic detection and removal of organic contaminants in water.Nature communications · 2026Article
- Site-Specific Ir Single Atoms in Spinel Induce 5d Spin Polarization for Enhanced Oxygen Evolution.Angewandte Chemie (International ed. in English) · 2026Article
- Orbital coupling in bridge-mediated FeCu dual-atom catalysts for water decontamination.Nature communications · 2026Article
- Electronic structure-driven sodiophilicity enables stable anode-free sodium batteries.Science advances · 2026Article
- Mitigating polymer-induced self-inhibition with microenvironment-decoupled Sn(II) single-atom catalysts for pollutant polymerization.Nature communications · 2026Article
- Superexchange-Assisted Fe(IV)=O Chain Formation on Scalable Iron Single-Atom Catalysts for Low-Chemical Water Purification in Flow.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Oxygen vacancy-rich spinel oxide drives phenol polymerization via direct oxidative transfer.Environmental science and ecotechnology · 2026Article
- Enthalpy-Driven Topological Programming of (TPMS)-Like Carbon Networks.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Cobalt Single-Atom Catalysts for Ultrafast Sulfamethoxazole Degradation: Unveiling the Chloride-Ion-Enhanced Formation of Co(IV)=O.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Polymerization-driven removal of pollutants in advanced oxidation processes (AOPs) offers a sustainable way for the simultaneous achievement of contamination abatement and resource recovery, supporting a low-carbon water purification approach. However, regulating such a process remains a great challenge due to the insufficient microscopic understanding of electronic structure-dependent reaction mechanisms. Herein, this work probes the origin of catalytic pollutant polymerization using a series of transition metal (Cu, Ni, Co, and Fe) single-atom catalysts and identifies the d-band center of active site as the key driver for polymerization transfer of pollutants. The high-valent metal-oxo species, produced via peroxymonosulfate activation, are found to trigger the pollutant removal via polymerization transfer. Phenoxyl radicals, identified by the innovative spin-trapping and quenching approaches, act as the key intermediate in the polymerization reactions. More importantly, the oxidation capacity of high-valent metal-oxo species can be facilely tuned by regulating their binding strength for peroxymonosulfate through d-band center modulation. A 100% polymerization transfer ratio is achieved by lowering the d-band center. This work presents a paradigm to dynamically modulate the electronic structure of high-valent metal-oxo species and optimize pollutant removal from wastewater via polymerization.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.