Evidence map›Paper›PMID 38478893›Full record

ArticleJournal of the American Chemical Society2024

Diaryldiazoketones as Effective Carbene Sources for Highly Selective Rh(II)-Catalyzed Intermolecular C-H Functionalization.

Terrence-Thang H Nguyen, Aaron T Bosse, Duc Ly, Camila A Suarez, Jiantao Fu, Kristin Shimabukuro, Djamaladdin G Musaev, Huw M L Davies

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Review
  2. Article
  3. Asymmetric C-H Functionalization ofJournal of the American Chemical Society · 2025
    Article
  4. Article
  5. Article
  6. Rh(II)-Catalyzed EnantioselectiveOrganic letters · 2024
    Article
  7. DJournal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Terrence-Thang H NguyenDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
Aaron T BosseDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.ORCID 0000-0003-1644-8005
Duc LyDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
Camila A SuarezDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
Jiantao FuDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.ORCID 0000-0002-1067-6915
Kristin ShimabukuroDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
Djamaladdin G MusaevDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.ORCID 0000-0003-1160-6131
Huw M L DaviesDepartment of Chemistry, Emory University, Atlanta, Georgia 30322, United States.ORCID 0000-0001-6254-9398

Funding

N-Sulfonyltriazoles as Carbene PrecursorsR01GM099142 · NIGMS · EMORY UNIVERSITY · PI DAVIES, HUW M · 2011 to 2023
$4.1M
NIGMS NIH HHS R01 GM099142
6 · The paper itself

Abstract

A novel donor/acceptor carbene intermediate has been developed using diaryldiazoketones as carbene precursors. In the presence of the chiral dirhodium catalyst, Rh

Identifiers

PMID38478893
PMCPMC10979447

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.