ArticleProceedings of the National Academy of Sciences of the United States of America2024
Grain boundary plasticity initiated by excess volume.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Amorphization-templated nanocrystallization endows TiNi alloys with ultrahigh strength and programmable superelasticity.Science advances · 2026Article
- A machine learning-based framework for mapping hydrogen at the atomic scale.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
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Authors and funding
10 authors.
Funding
Abstract
Grain boundaries (GBs) serve not only as strong barriers to dislocation motion, but also as important carriers to accommodate plastic deformation in crystalline solids. During deformation, the inherent excess volume associated with loose atomic packing in GBs brings about a microscopic degree of freedom that can initiate GB plasticity, which is beyond the classic geometric description of GBs. However, identification of this atomistic process has long remained elusive due to its transient nature. Here, we use Au polycrystals to unveil a general and inherent route to initiating GB plasticity via a transient topological transition process triggered by the excess volume. This route underscores the general impact of a microscopic degree of freedom which is governed by a stress-triaxiality-based criterion. Our findings provide a missing perspective for developing a more comprehensive understanding of the role of GBs in plastic deformation.
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