ArticleNature communications2024
Complete separation of benzene-cyclohexene-cyclohexane mixtures via temperature-dependent molecular sieving by a flexible chain-like coordination polymer.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Construction of molecular fans in metal-organic framework to overcome diffusion resistance for trace benzene capture.Nature communications · 2026Article
- Crystal Engineering of Chelating Hybrid Ultramicroporous Materials via Pillar Modulation for Energy-Efficient Acetylene Separation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- An aqueous in situ approach to discover crystalline coordination materials for adsorptive separation.Nature communications · 2026Article
- Rational design of a polyphenyl octacarboxylate HOF for highly selective separation of benzene over cyclohexane.Chemical science · 2026Article
- Discrimination of Hexane Isomers by Temperature Swing Adsorption in a Rigid Aluminum Metal-Organic Framework.ACS materials letters · 2026Article
- Silver-Based Alcohol-Functionalized Solvent for Efficient Separation of Olefins.Chem & bio engineering · 2026Article
- Heterometallic 3-D Zn/Ca Metal-Organic Frameworks Based on V-Shaped Angular Tetracarboxylic Ligands as Selective Fluorescence Sensors for Nitroaromatic Explosive Vapors.Inorganic chemistry · 2025Article
- A 1D [Ni(L)(HMolecules (Basel, Switzerland) · 2025Article
- Flexible Metal-Organic Frameworks for Adsorptive Separation of Liquid Hydrocarbons.Accounts of chemical research · 2025Article
- Effect of Entropic Constraints on the Thermodynamics of Molecular Adsorption in Nano-Porous Materials.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Flue gas desulfurization and SONature chemistry · 2025Article
- Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal-Organic Frameworks.Nano-micro letters · 2025Review
- Rapid extraction of trace benzene by a crown-ether-based metal-organic framework.National science review · 2024Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
The separation and purification of C6 cyclic hydrocarbons (benzene, cyclohexene, cyclohexane) represent a critically important but energy intensive process. Developing adsorptive separation technique to replace thermally driven distillation processes holds great promise to significantly reduce energy consumption. Here we report a flexible one-dimensional coordination polymer as an efficient adsorbent to discriminate ternary C6 cyclic hydrocarbons via an ideal molecular sieving mechanism. The compound undergoes fully reversible structural transformation associated with removal/re-coordination of water molecules and between activated and hydrocarbon-loaded forms. It exhibits distinct temperature- and adsorbate-dependent adsorption behavior which facilitates the complete separation of benzene, cyclohexene and cyclohexane from their binary and ternary mixtures, with the record-high uptake ratios for C
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