ArticleJournal of the American Chemical Society2024
Porous and Meltable Metal-Organic Polyhedra for the Generation and Shaping of Porous Mixed-Matrix Composites.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Polymer-Grafted Cu(II) Metal-Organic Polyhedra as Scalable, Melt-Processable Porous Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Low-Valent Rhodium and Iridium Assemblies Directed by Uracilate and Guaninate Linkers.Inorganic chemistry · 2026Article
- Transferring Porosity Across Physical States Using Metal-Organic Cages: Porous Liquids, Glasses, Rubbers, and More.Angewandte Chemie (International ed. in English) · 2026Review
- Functional Post-Synthetic Chemistry of Metal-Organic Cages According to Molecular Architecture and Specific Geometry of Origin.Molecules (Basel, Switzerland) · 2025Review
- Functional metal-organic liquids.Chemical science · 2024Review
Corrections and comments
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Authors and funding
9 authors.
Funding
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Abstract
Here, we report the synthesis of BCN-93, a meltable, functionalized, and permanently porous metal-organic polyhedron (MOP) and its subsequent transformation into amorphous or crystalline, shaped, self-standing, transparent porous films via melting and subsequent cooling. The synthesis entails the outer functionalization of a MOP with meltable polymer chains: in our model case, we functionalized a Rh(II)-based cuboctahedral MOP with poly(ethylene glycol). Finally, we demonstrate that once melted, BCN-93 can serve as a porous matrix into which other materials or molecules can be dispersed to form mixed-matrix composites. To illustrate this, we combined BCN-93 with one of various additives (either two MOF crystals, a porous cage, or a linear polymer) to generate a series of mixed-matrix films, each of which exhibited greater CO
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Registered trials
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