Evidence map›Paper›PMID 38455009›Full record

ArticleChemical science2024

Regulating luminescence thermal enhancement in negative thermal expansion metal-organic frameworks.

Liang Chen, Yili Cao, Rui Ma, Hongmei Cao, Xin Chen, Kun Lin, Qiang Li, Jinxia Deng, Chunyu Liu, Yilin Wang and 2 more

Abstract read

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Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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4 · The record

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5 · Who and what money

Authors and funding

12 authors.

Liang ChenBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Yili CaoBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Rui MaBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Hongmei CaoBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Xin ChenBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.ORCID https://orcid.org/0000-0003-1779-1091

Kun LinBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Qiang LiBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.ORCID https://orcid.org/0000-0003-4259-6984

Jinxia DengBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.

Chunyu LiuDepartment of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Tsinghua University 100084 Beijing China.

Yilin WangInstitute of Advanced Materials, Nanjing Tech University 211816 Nanjing China iamlhuang@njtech.edu.cn.ORCID https://orcid.org/0000-0002-9054-353X

Ling HuangInstitute of Advanced Materials, Nanjing Tech University 211816 Nanjing China iamlhuang@njtech.edu.cn.ORCID https://orcid.org/0000-0003-1244-3522

Xianran XingBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.ORCID https://orcid.org/0000-0003-0704-8886

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Overcoming thermal quenching is generally essential for the practical application of luminescent materials. It has been recently found that frameworks with negative thermal expansion (NTE) could be a promising candidate to engineer unconventional luminescence thermal enhancement. However, the mechanism through which luminescence thermal enhancement can be well tuned remains an open issue. In this work, enabled by altering ligands in a series of UiO-66 derived Eu-based metal-organic frameworks, it was revealed that the changes in the thermal expansion are closely related to luminescence thermal enhancement. The NTE of the aromatic ring part favors luminescence thermal enhancement, while contraction of the carboxylic acid part plays the opposite role. Modulation of functional groups in ligands can change the thermal vibration of aromatic rings and then achieve luminescence thermal enhancement in a wide temperature window. Our findings pave the way to manipulate the NTE and luminescence thermal enhancement based on ligand engineering.

Identifiers

PMID38455009

DOI10.1039/d3sc06710f

PMCPMC10915847

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LicenceCC BY-NC

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.