ArticleACS catalysis2024
Sustainable Electrosynthesis of Cyclohexanone Oxime through Nitrate Reduction on a Zn-Cu Alloy Catalyst.
Article in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Steering C-N coupling pathway on spatial-separated zinc dual sites for efficient oxime electrosynthesis.Nature communications · 2026Article
- Electrocatalytic Oxyanion Reduction: From Fundamental Principles to Rational Catalyst Design.Topics in current chemistry (Cham) · 2026Review
- Metal-defect pairs for near-stoichiometric electrocatalytic C-N coupling.National science review · 2026Article
- High-Rate, Selective Electrosynthesis of Cyclohexanone Oxime via In Situ Generation and Release of Hydroxylamine on Bismuth.Journal of the American Chemical Society · 2026Article
- The Role of Local pH in Electrocatalysis: Measurement, Impact, and Control Strategies.ACS electrochemistry · 2026Review
- Inter-Atomic Synergy on Single-Atom Alloy Promotes Cyclohexanone Oxime Electrosynthesis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Integrated electrochemical porous solid electrolyte reactor and packed bed reactor for efficient synthesis of nylon-6 precursor.Nature communications · 2026Article
- Sustainable Electrosynthesis of Propylamines through Nitrogen Reduction on a MoSACS electrochemistry · 2026Article
- Reductive Nitrogen Species Activation via Pulsed Electrolysis: Recent Advances and Future Prospects.Angewandte Chemie (International ed. in English) · 2025Review
- Hydroxyl and nitrate co-upgrading to oxime via anode-cathode cascade electrolyzer.Nature communications · 2025Article
- Selective Stepwise Reduction of Nitrate and Nitrite to Dinitrogen or Ammonia.Journal of the American Chemical Society · 2025Article
- Effective Nitrate Electroconversion to Ammonia Using an Entangled CoACS applied materials & interfaces · 2025Article
- Achieving over 90% Faradaic Efficiency in Cyclohexanone Oxime Electrosynthesis Using the Cu-Mo Dual-Site Catalyst.Journal of the American Chemical Society · 2024Article
- Upgrading of nitrate to hydrazine through cascading electrocatalytic ammonia production with controllable N-N coupling.Nature communications · 2024Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Cyclohexanone oxime is an important precursor for Nylon-6 and is typically synthesized via the nucleophilic addition-elimination of hydroxylamine with cyclohexanone. Current technologies for hydroxylamine production are, however, not environment-friendly due to the requirement of harsh reaction conditions. Here, we report an electrochemical method for the one-pot synthesis of cyclohexanone oxime under ambient conditions with aqueous nitrate as the nitrogen source. A series of Zn-Cu alloy catalysts are developed to drive the electrochemical reduction of nitrate, where the hydroxylamine intermediate formed in the electroreduction process can undergo a chemical reaction with the cyclohexanone present in the electrolyte to produce the corresponding oxime. The best performance is achieved on a Zn
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