ArticleProceedings of the National Academy of Sciences of the United States of America2024
Tailoring the aluminum nanocrystal surface oxide for all-aluminum-based antenna-reactor plasmonic photocatalysts.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Atomistic Theory of Hot-Carrier Generation in Aluminum Nanoparticles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Polyelemental Nanoparticle Synthesis Enabled by Noncontact Metallothermic Reactions.Journal of the American Chemical Society · 2025Article
- Deciphering the Photocatalysis Mechanism of Semimetallic Bismuth Nanoparticles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Influence of Surface Chemistry on Metal Deposition Outcomes in Copper Selenide-Based Nanoheterostructure Synthesis.Langmuir : the ACS journal of surfaces and colloids · 2024Article
Corrections and comments
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Authors and funding
17 authors.
Funding
Abstract
Aluminum nanocrystals (AlNCs) are of increasing interest as sustainable, earth-abundant nanoparticles for visible wavelength plasmonics and as versatile nanoantennas for energy-efficient plasmonic photocatalysis. Here, we show that annealing AlNCs under various gases and thermal conditions induces substantial, systematic changes in their surface oxide, modifying crystalline phase, surface morphology, density, and defect type and concentration. Tailoring the surface oxide properties enables AlNCs to function as all-aluminum-based antenna-reactor plasmonic photocatalysts, with the modified surface oxides providing varying reactivities and selectivities for several chemical reactions.
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