ArticleNature communications2024
Influence of electric double layer rigidity on CO adsorption and electroreduction rate.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
12 citing papers in PubMed.
- Editable Hydrogen Bond Network Within the Electric Double Layer for COAngewandte Chemie (International ed. in English) · 2026Article
- Effects of Outer Helmholtz Plane-Located Anions on the Oxygenate Adsorption and Oxygen Reduction Catalysis on Pt(111).JACS Au · 2026Article
- Synergistic cation-facet effects boost alkaline hydrogen evolution kinetics on stepped Pt surfaces.Communications chemistry · 2026Article
- Behavior Regulation of *CO over Self-Evolution Tandem Catalysts Under Tuned Interfacial Electric Field Boosts COAngewandte Chemie (International ed. in English) · 2025Article
- Insight into the Carbon Monoxide Reduction Reaction on Cu(111) from Operando Electrochemical X-ray Photoelectron Spectroscopy.Angewandte Chemie (International ed. in English) · 2025Article
- Electrochemical Cell Designs for Efficient Carbon Dioxide Reduction and Water Electrolysis: Status and Perspectives.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Decoding Double Layer Dynamics forAngewandte Chemie (International ed. in English) · 2025Article
- Scaled CO Electroreduction to Alcohols.Nature communications · 2025Article
- Electrolyte Effect on Electrocatalytic CONanomaterials (Basel, Switzerland) · 2025Review
- Multiscale Modeling of COChemSusChem · 2025Review
- Plasmon Enhanced IR Spectroelectrochemistry.ACS measurement science au · 2024Review
- Energy-efficient CONature communications · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
Understanding the structure of the electric double layer (EDL) is critical for designing efficient electrocatalytic processes. However, the interplay between reactant adsorbates and the concentrated ionic species within the EDL remains an aspect that has yet to be fully explored. In the present study, we employ electrochemical CO reduction on Cu as a model reaction to reveal the significant impact of EDL structure on CO adsorption. By altering the sequence of applying negative potential and elevating CO pressure, we discern two distinct EDL structures with varying cation density and CO coverage. Our findings demonstrate that the EDL comprising densely packed cations substantially hinders CO adsorption on the Cu as opposed to the EDL containing less compact cations. These two different EDL structures remained stable over the course of our experiments, despite their identical initial and final conditions, suggesting an insurmountable kinetic barrier present in between. Moreover, we show that the size and identity of cations play decisive roles in determining the properties of the EDL in CO electroreduction on Cu. This study presents a refined adaptation of the classical Gouy-Chapman-Stern model and highlights its catalytic importance, which bridges the mechanistic gap between the EDL structure and cathodic reactions.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.