Evidence map›Paper›PMID 38425382›Full record

ArticleOrganometallics2024

Phosphinoyl-Substituted Ketenyl Anions: Synthesis and Substituent Effects on the Structural Properties.

Mike Jörges, Sunita Mondal, Manoj Kumar, Prakash Duari, Felix Krischer, Julian Löffler, Viktoria H Gessner

Abstract read
In one paragraph

Article in Organometallics, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Isolable C-Phosphonio-Boratavinyl Anion.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Article
  4. Article
  5. Activation of NDalton transactions (Cambridge, England : 2003) · 2026
    Article
  6. The Pyridylketenyl Anion: Entry to Diverse N-Heterocycles.Journal of the American Chemical Society · 2026
    Article
  7. Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity.Angewandte Chemie (International ed. in English) · 2025
    Article
  8. Article
  9. Article
  10. Covalent capture of nitrous oxide by phosphanides.Chemical communications (Cambridge, England) · 2025
    Article
  11. Review
  12. PPhAngewandte Chemie (International ed. in English) · 2025
    Article
  13. An Azide-Free Synthesis of Metallodiazomethanes Using Nitrous Oxide.Journal of the American Chemical Society · 2024
    Article
  14. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Mike JörgesFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Sunita MondalFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Manoj KumarFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Prakash DuariFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Felix KrischerFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Julian LöfflerFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Viktoria H GessnerFaculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.ORCID https://orcid.org/0000-0001-6557-2366

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Ketenyl anions are versatile intermediates in synthetic chemistry and have recently become accessible as isolable reagents from metalated ylides by exchange of the phosphine with CO. Herein, we report on a systematic study of substituent effects on the structure and bonding situation in ketenyl anions. A series of phosphinoyl-substituted ketenyl anions {[R

Identifiers

PMID38425382
PMCPMC10900514

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.