ArticleThe journal of physical chemistry letters2024
Internal Secondary Relaxation as a Dielectric Probe of Molecular Surroundings.
Article in The journal of physical chemistry letters, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- A Fresh Perspective on the Internal Plasticizing Effect in Non-Polymeric Glass-Formers.The journal of physical chemistry. B · 2025Article
- Engineering of Rotational Dynamics via Polymorph Manipulation.The journal of physical chemistry. A · 2024Article
- Dual Nature of Large and Anisotropic Glass-Forming Molecules in Terms of Debye-Stokes-Einstein Relation Revealed.The journal of physical chemistry. B · 2024Article
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We investigated the secondary relaxation behavior in rotor molecules in a glassy and crystalline state by using the dielectric method. Without changing the molecular source of secondary relaxation, only by modifying the environment around the rotating unit we observed notable variations in spectral parameters. Our results show that internal rotation, like a probe, can sample the immediate surroundings with high sensitivity to molecular-level changes that impact the rotation parameters. Our research offers a new perspective on the dielectric behavior of internal secondary relaxations and challenges the paradigm of their irrelevant nature.
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Registered trials
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