Synthesis and Dynamic Behavior of Ce(IV) Double-Decker Complexes of Sterically Hindered Phthalocyanines.

Jeevithra Dewi Subramaniam, Toshio Nishino, Kazuma Yasuhara, Gwénaël Rapenne

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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5 · Who and what money

Authors and funding

4 authors.

Jeevithra Dewi SubramaniamDivision of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma 630-0192, Japan.ORCID 0009-0006-5799-1433

Toshio NishinoDivision of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma 630-0192, Japan.ORCID 0000-0001-9198-8867

Kazuma YasuharaDivision of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma 630-0192, Japan.

Gwénaël RapenneDivision of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma 630-0192, Japan.ORCID 0000-0002-4993-4213

Funding

Japan Society for the Promotion of Science 20K21131Japan Society for the Promotion of Science 22H00325Japan Society for the Promotion of Science 23K13560

6 · The paper itself

Abstract

Phthalocyanines and their double-decker complexes are interesting in designing rotative molecular machines, which are crucial for the development of molecular motors and gears. This study explores the design and synthesis of three bulky phthalocyanine ligands functionalized at the α-positions with phenothiazine or carbazole fragments, aiming to investigate dynamic rotational motions in these sterically hindered molecular complexes. Homoleptic and heteroleptic double-decker complexes were synthesized through the complexation of these ligands with Ce(IV). Notably,

Indexed as

carbazolecerium iondouble-decker complexheteroleptichomolepticligand rotationphenothiazinephthalocyanine

Identifiers

PMID38398640

DOI10.3390/molecules29040888

PMCPMC10891708

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