Evidence map›Paper›PMID 38384732›Full record

ArticleCrystEngComm2024

Polymorphism and orientation control of copper-dicarboxylate metal-organic framework thin films through vapour- and liquid-phase growth.

Víctor Rubio-Giménez, Francesco Carraro, Sebastian Hofer, Mario Fratschko, Timothée Stassin, Sabina Rodríguez-Hermida, Benedikt Schrode, Luisa Barba, Roland Resel, Paolo Falcaro and 1 more

Abstract read
In one paragraph

Article in CrystEngComm, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Víctor Rubio-GiménezCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium victorrubio.gimenez@kuleuven.be rob.ameloot@kuleuven.be.ORCID https://orcid.org/0000-0003-1269-5885
Francesco CarraroInstitute of Physical and Theoretical Chemistry, Graz University of Technology Stremayrgasse 9/Z2 8010 Graz Austria paolo.falcaro@tugraz.at.ORCID https://orcid.org/0000-0001-8485-4676
Sebastian HoferInstitute of Solid State Physics, Graz University of Technology Petersgasse 16 8010 Graz Austria roland.resel@tugraz.at.
Mario FratschkoInstitute of Solid State Physics, Graz University of Technology Petersgasse 16 8010 Graz Austria roland.resel@tugraz.at.
Timothée StassinCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium victorrubio.gimenez@kuleuven.be rob.ameloot@kuleuven.be.ORCID https://orcid.org/0000-0002-1175-4057
Sabina Rodríguez-HermidaCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium victorrubio.gimenez@kuleuven.be rob.ameloot@kuleuven.be.
Benedikt SchrodeInstitute of Solid State Physics, Graz University of Technology Petersgasse 16 8010 Graz Austria roland.resel@tugraz.at.ORCID https://orcid.org/0000-0003-2013-9272
Luisa BarbaIstituto di Cristallografia - Sincrotrone Elettra, Consiglio Nazionale delle Ricerche Area Science Park 34142 Basovizza Italy.ORCID https://orcid.org/0000-0001-8832-7056
Roland ReselInstitute of Solid State Physics, Graz University of Technology Petersgasse 16 8010 Graz Austria roland.resel@tugraz.at.ORCID https://orcid.org/0000-0003-0079-3525
Paolo FalcaroInstitute of Physical and Theoretical Chemistry, Graz University of Technology Stremayrgasse 9/Z2 8010 Graz Austria paolo.falcaro@tugraz.at.ORCID https://orcid.org/0000-0001-5935-0409
Rob AmelootCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium victorrubio.gimenez@kuleuven.be rob.ameloot@kuleuven.be.ORCID https://orcid.org/0000-0003-3178-5480

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Precise control over the crystalline phase and crystallographic orientation within thin films of metal-organic frameworks (MOFs) is highly desirable. Here, we report a comparison of the liquid- and vapour-phase film deposition of two copper-dicarboxylate MOFs starting from an oriented metal hydroxide precursor. X-ray diffraction revealed that the vapour- or liquid-phase reaction of the linker with this precursor results in different crystalline phases, morphologies, and orientations. Pole figure analysis showed that solution-based growth of the MOFs follows the axial texture of the metal hydroxide precursor, resulting in heteroepitaxy. In contrast, the vapour-phase method results in non-epitaxial growth with uniplanar texture only.

Identifiers

PMID38384732
PMCPMC10877460

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.