ArticleInorganic chemistry2024
Light Activation and Photophysics of a Structurally Constrained Nickel(II)-Bipyridine Aryl Halide Complex.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed, 13 citations in OpenAlex.
- Unlocking Distinct Excited States of a Nickel(II) Complex Without Modulating the Primary Coordination Sphere.JACS Au · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Ultrafast Population and Structural Dynamics of a Ni-Bipyridine Photoredox Catalyst Reveal a Significant Deactivation Pathway.The journal of physical chemistry letters · 2026Article
- Dual Catalytic Enantioconvergent Carbamoylation of Aziridines.Journal of the American Chemical Society · 2025Article
- Light-Promoted C(spJournal of the American Chemical Society · 2025Article
- Mechanisms of Photoredox Catalysis Featuring Nickel-Bipyridine Complexes.ACS catalysis · 2024Review
- Ultrafast Photophysics of Ni(I)-Bipyridine Halide Complexes: Spanning the Marcus Normal and Inverted Regimes.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 2 countries.
Funding
Abstract
Transition-metal photoredox catalysis has transformed organic synthesis by harnessing light to construct complex molecules. Nickel(II)-bipyridine (bpy) aryl halide complexes are a significant class of cross-coupling catalysts that can be activated via direct light excitation. This study investigates the effects of molecular structure on the photophysics of these catalysts by considering an underexplored, structurally constrained Ni(II)-bpy aryl halide complex in which the aryl and bpy ligands are covalently tethered alongside traditional unconstrained complexes. Intriguingly, the tethered complex is photochemically stable but features a reversible Ni(II)-C(aryl) ⇄ [Ni(I)···C(aryl)
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.