ArticleNature chemistry2024
Tunable valence tautomerism in lanthanide-organic alloys.
Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Persistent compensated ferrimagnetism in the molecular framework Cr(pyrazine)Nature chemistry · 2026Article
- Chemical Engineering of Altermagnetism in Two-Dimensional Metal-Organic Frameworks.Journal of the American Chemical Society · 2026Article
- Leveraging the redox activities of cerium and dibenzotetrathiafulvalene to discover a photo-responsive magnetic material.Chemical science · 2026Article
- Giant Magnetostriction in Ferrimagnetic SmFeAngewandte Chemie (International ed. in English) · 2026Article
- Pressure-Induced Reduction of Dicyanamide by Samarium(II) in a Coordination Polymer.Inorganic chemistry · 2026Article
- A photochromic trinuclear dysprosium(iii) single-molecule magnet with two distinct relaxation processes.RSC advances · 2024Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
The inimitable electronic structures of the lanthanide (Ln) ions are key to advanced materials and technologies involving these elements. The trivalent ions are ubiquitous and are used much more widely than the divalent and tetravalent analogues, which possess vastly different optical and magnetic properties. Hence, alteration of the valence electron count by external stimuli can lead to dramatic changes in materials properties. Compounds exhibiting a temperature-induced complete Ln(III) ⇄ Ln(II) switch, referred to as a valence tautomeric (VT) transition, are rare. Here we present an abrupt and hysteretic VT transition in a lanthanide-based coordination polymer, SmI
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.