A Comprehensive Review on the Boosted Effects of Anion Vacancy in the Heterogeneous Photocatalytic Degradation, Part II: Focus on Oxygen Vacancy.

Environmental problems, including the increasingly polluted water and the energy crisis, have led to a need to propose novel strategies/methodologies to contribute to sustainable progress and enhance human well-being. For these goals, heterogeneous semiconducting-based photocatalysis is introduced as a green, eco-friendly, cost-effective, and effective strategy. The introduction of anion vacancies in semiconductors has been well-known as an effective strategy for considerably enhancing the photocatalytic activity of such photocatalytic systems, giving them the advantages of promoting light harvesting, facilitating photogenerated electron-hole pair separation, optimizing the electronic structure, and enhancing the yield of reactive radicals. This Review will introduce the effects of anion vacancy-dominated photodegradation systems. Then, their mechanism will illustrate how an anion vacancy changes the photodegradation pathway to enhance the degradation efficiency toward pollutants and the overall photocatalytic performance. Specifically, the vacancy defect types and the methods of tailoring vacancies will be briefly illustrated, and this part of the Review will focus on the oxygen vacancy (OV) and its recent advances. The challenges and development issues for engineered vacancy defects in photocatalysts will also be discussed for practical applications and to provide a promising research direction. Finally, some prospects for this emerging field will be proposed and suggested. All permission numbers for adopted figures from the literature are summarized in a separate file for the Editor.