ArticleMacromolecules2024
Keto-Polyethylenes with Controlled Crystallinity and Materials Properties from Catalytic Ethylene-CO-Norbornene Terpolymerization.
Article in Macromolecules, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed, 18 citations in OpenAlex.
- Vanadium(V) Complexes Bearing Bidentate Phenoxy-Phosphine Ligands and Their High Performance Toward Ethylene Homopolymerization.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Microstructure of amide-functionalized polyethylenes determined by NMR relaxometry.Chemical science · 2026Article
- Advances in sustainable polyolefins: synthesis, chemical transformation and recycling.National science review · 2025Review
- Exploring the role of MgO nanoparticles in the mechanical properties of the MgO/PE composite: a tight-binding and molecular dynamics simulation study.RSC advances · 2025Article
- Installing a Trigger to Upcycle High-Density Polyethylene.Journal of the American Chemical Society · 2024Article
- Recent Advances in Nickel Catalysts with Industrial Exploitability for Copolymerization of Ethylene with Polar Monomers.Polymers · 2024Review
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Recent advances in Ni(II) catalyzed, nonalternating catalytic copolymerization of ethylene with carbon monoxide (CO) enable the synthesis of in-chain keto-functionalized polyethylenes (keto-PEs) with high-density polyethylene-like materials properties. Addition of norbornene as a bulky, noncrystallizable comonomer during catalytic polymerization allows tuning of the crystallinity in these keto-PE materials by randomly incorporated norbornene units in the polymer chain, while molecular weights are not adversely affected. Such crystallinity-reduced keto-PEs are characterized as softer materials with better ductility and may therefore be more suited for, e.g., potential film applications.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.