Evidence map›Paper›PMID 38368421›Full record

ArticleNature communications2024

Elucidation of the role of metals in the adsorption and photodegradation of herbicides by metal-organic frameworks.

Nan Chieh Chiu, Jacob M Lessard, Emmanuel Nyela Musa, Logan S Lancaster, Clara Wheeler, Taylor D Krueger, Cheng Chen, Trenton C Gallagher, Makenzie T Nord, Hongliang Huang and 3 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Air-Insensitive Sulfonylation Enabled by a MOF-Supported Nickel Photocatalyst.Small (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  7. Degradation of Glyphosate to Benign N-Formyl Glycine Using MOF-808 Nanocrystals.Angewandte Chemie (International ed. in English) · 2025
    Article
  8. Article
  9. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Nan Chieh Chiu *Materials Discovery Laboratory (MaD Lab), Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Jacob M Lessard *Materials Discovery Laboratory (MaD Lab), Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Emmanuel Nyela Musa *Materials Discovery Laboratory (MaD Lab), Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Logan S LancasterDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.ORCID http://orcid.org/0000-0002-8620-3006
Clara WheelerDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Taylor D KruegerDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Cheng ChenDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Trenton C GallagherDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.
Makenzie T NordDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA.ORCID http://orcid.org/0000-0003-1903-7543
Hongliang HuangState Key Laboratory of Separation Membranes and Membrane Processes, School of Chemical Engineering and Technology, Tiangong University, 300387, Tianjin, China. huanghongliang@tiangong.edu.cn.ORCID http://orcid.org/0000-0001-9690-9259
Paul Ha-Yeon CheongDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA. cheongh@oregonstate.edu.ORCID http://orcid.org/0000-0001-6705-2962
Chong FangDepartment of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA. chong.fang@oregonstate.edu.ORCID http://orcid.org/0000-0002-8879-1825
Kyriakos C StylianouMaterials Discovery Laboratory (MaD Lab), Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR, 97331, USA. kyriakos.stylianou@oregonstate.edu.ORCID http://orcid.org/0000-0003-1670-0020

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here, four MOFs, namely Sc-TBAPy, Al-TBAPy, Y-TBAPy, and Fe-TBAPy (TBAPy: 1,3,6,8-tetrakis(p-benzoic acid)pyrene), were characterized and evaluated for their ability to remediate glyphosate (GP) from water. Among these materials, Sc-TBAPy demonstrates superior performance in both the adsorption and degradation of GP. Upon light irradiation for 5 min, Sc-TBAPy completely degrades 100% of GP in a 1.5 mM aqueous solution. Femtosecond transient absorption spectroscopy reveals that Sc-TBAPy exhibits enhanced charge transfer character compared to the other MOFs, as well as suppressed formation of emissive excimers that could impede photocatalysis. This finding was further supported by hydrogen evolution half-reaction (HER) experiments, which demonstrated Sc-TBAPy's superior catalytic activity for water splitting. In addition to its faster adsorption and more efficient photodegradation of GP, Sc-TBAPy also followed a selective pathway towards the oxidation of GP, avoiding the formation of toxic aminomethylphosphonic acid observed with the other M

Identifiers

PMID38368421
PMCPMC10874385

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.