Evidence map›Paper›PMID 38363862›Full record

ArticleJournal of the American Chemical Society2024

Stability and Reactivity of Aromatic Radical Anions in Solution with Relevance to Birch Reduction.

Tatiana Nemirovich, Brandon Young, Krystof Brezina, Philip E Mason, Robert Seidel, Dominik Stemer, Bernd Winter, Pavel Jungwirth, Stephen E Bradforth, H Christian Schewe

Open access · hybridAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
2.7field-weighted citation impact, top 10% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 6 citations in OpenAlex.

  1. A Mesoionic Platform for Persistent Anionic Nitrogen-Centered Radicals.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Annulated Radical Cations with a CAngewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 5 institutions in 3 countries.

Tatiana NemirovichInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic.ORCID 0000-0003-4142-2616
Brandon YoungDepartment of Chemistry, University of Southern California, Los Angeles, California 90089, United States.
Krystof BrezinaInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic.ORCID 0000-0003-0285-1282
Philip E MasonInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic.
Robert SeidelHelmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany.ORCID 0000-0003-2613-4106
Dominik StemerFritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.ORCID 0000-0002-5528-1773
Bernd WinterFritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.ORCID 0000-0002-5597-8888
Pavel JungwirthInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic.ORCID 0000-0002-6892-3288
Stephen E BradforthDepartment of Chemistry, University of Southern California, Los Angeles, California 90089, United States.ORCID 0000-0002-6164-3347
H Christian ScheweInstitute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic.ORCID 0000-0003-3232-5486
Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry · CZFritz Haber Institute of the Max Planck Society · DEUniversity of Southern California · USCzech Academy of Sciences, J. Heyrovský Institute of Physical Chemistry · CZHelmholtz-Zentrum Berlin für Materialien und Energie · DE

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We investigate the electronic structure of aromatic radical anions in the solution phase employing a combination of liquid-jet (LJ) photoelectron (PE) spectroscopy measurements and electronic structure calculations. By using recently developed protocols, we accurately determine the vertical ionization energies of valence electrons of both the solvent and the solute molecules. In particular, we first characterize the pure solvent of tetrahydrofuran (THF) by LJ-PE measurements in conjunction with ab initio molecular dynamics simulations and G

Identifiers

PMID38363862
PMCPMC10979400
OpenAlexW4391877783

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.