ArticleOrganometallics2024
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines.
Article in Organometallics, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed, 7 citations in OpenAlex.
- Broadly Accessible and Highly Active Hydrophosphination Catalysis With Simple Calcium Compounds in DMSO Solution.ChemSusChem · 2026Article
- Catalytic Nitrous Oxide Degradation with Group 15 Clusters.Journal of the American Chemical Society · 2025Article
- A Remarkable Catalyst-Free Photochemical Alkene Hydrophosphination with Bis(trimethylsilyl)phosphonite.JACS Au · 2025Article
- Zintl Clusters as a Platform for Lewis Acid Catalysis.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Although Zintl ions and phases have been known for more than a century, their application as tools to build organic molecules is underdeveloped. Here, a range of Zintl ions and phases were surveyed in the hydrophosphination of alkynes, alkenes, and imines with diphenylphosphine to afford useful organophosphine products. Further investigations with diphenylphosphine in the absence of the unsaturated organic substrates revealed the formation of the diphenylphosphide anion, allowing for the conclusion that the role of the Zintl species is as an initiator in these transformations.
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Registered trials
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