Evidence map›Paper›PMID 38344401›Full record

ArticleChemistry of materials : a publication of the American Chemical Society2023

Vapor-Assisted Conversion of Heterobimetallic Titanium-Organic Framework Thin Films.

María Romero-Ángel, Víctor Rubio-Giménez, Eloy P Gómez-Oliveira, Margot F K Verstreken, Jorid Smets, Jesús Gándara-Loe, Natalia M Padial, Rob Ameloot, Sergio Tatay, Carlos Martí-Gastaldo

Open access · hybridAbstract read
In one paragraph

Article in Chemistry of materials : a publication of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.1field-weighted citation impact, top 58% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 1 citations in OpenAlex.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 2 institutions in 2 countries.

María Romero-ÁngelInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.
Víctor Rubio-GiménezInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.ORCID https://orcid.org/0000-0003-1269-5885
Eloy P Gómez-OliveiraInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.
Margot F K VerstrekenCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium.
Jorid SmetsCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium.ORCID https://orcid.org/0000-0003-4719-7368
Jesús Gándara-LoeCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium.ORCID https://orcid.org/0000-0003-1334-4788
Natalia M PadialInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.ORCID https://orcid.org/0000-0001-6067-3360
Rob AmelootCentre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium.ORCID https://orcid.org/0000-0003-3178-5480
Sergio TatayInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.ORCID https://orcid.org/0000-0003-0785-866X
Carlos Martí-GastaldoInstituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.ORCID https://orcid.org/0000-0003-3203-0047
Parc Científic de la Universitat de València · ESKU Leuven · BE

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Heterobimetallic Metal-Organic Frameworks (MOFs) synergically combine the properties of two metal ions, thus offering significant advantages over homometallic MOFs in gas storage, separation, and catalysis, among other applications. However, these remain centered on bulk materials, while applications that require functional coatings on solid supports are not developed. We explore for the first time the deposition of heterometallic Ti-based MOF thin films using vapor-assisted conversion on substrates functionalized with a self-assembled monolayer. Furthermore, metal-induced dynamic topological transformation allows the conversion of MUV-10(Ca) films into MUV-101(Co) and MUV-102(Cu), which is not accessible through direct synthesis, without morphologically altering the films. These nonconventional thin-film deposition techniques enable homogeneous and crystalline coatings of heterometallic titanium MOFs that also maintain their corresponding porosity.

Identifiers

PMID38344401
PMCPMC10853932
OpenAlexW4389552582

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.