ArticleChem2024
Miniaturized enantioselective tubular devices for the electromechanical wireless separation of chiral analytes.
Article in Chem, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Upcycling eggshell waste into sustainable and portable chiral membranes for the physical separation and electrocatalytic deracemization of enantiomers.RSC advances · 2026Article
- Unplugging Asymmetric Synthesis with a Wireless, Self-Pumping Electrochemical Reactor.Journal of the American Chemical Society · 2025Article
- Tunable stereoselectivity in a wireless electrochemical microreactor using natural chiral ionic liquids.Green chemistry : an international journal and green chemistry resource : GC · 2025Article
- Stirring Without Stirrers: Polymer Fouling-Driven Mass Transport Unlocks Order-of-Magnitude Gain in Electrochemiluminescence.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Unconventional approaches for chiral resolution.Analytical and bioanalytical chemistry · 2024Review
- Wireless Hollow Miniaturized Objects for Electroassisted Chiral Resolution.Analytical chemistry · 2024Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chirality plays a crucial role in different research fields, ranging from fundamental physico-chemistry to applied aspects in materials science and medicine. In this context, enantioselective loading and pumping of chiral analytes for analysis, separation, and cargo delivery applications is an interesting scientific challenge. Herein, we introduce artificial chiral soft electromechanical pumps based on a bi-layer film built up by electrodepositing polypyrrole and an inherently chiral conducting oligomer at its internal surface. The enantioselective device can be driven by bipolar electrochemistry to act as a pump, allowing the selective loading and separation of different chiral analytes injected as pure enantiomers and in racemic form (i.e., doxorubicin, a chemotherapy drug, limonene, carvone, and a chiral ferrocene). The synergy between wireless electromechanical actuation and inherent enantiodiscrimination features makes these actuators excellent candidates for the controlled handling of chiral molecules in the frame of potential applications ranging from analysis to drug delivery.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.