ArticleNature communications2024
Separation of benzene and toluene associated with vapochromic behaviors by hybrid[4]arene-based co-crystals.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Surface co-crystallization with an organic single crystal enables vapochromic and luminescent detection of phenols.Chemical science · 2026Article
- Guest-dependent solid-state superstructure plasticity and its application to adsorptive benzene sieving.Chemical science · 2026Article
- Inclusion co-crystals based on Tröger's base molecular box for thermally activated delayed fluorescence.Nature communications · 2026Article
- Cyano-Mediated Donor-Acceptor Engineering: A Rational Strategy to Boost Charge Transfer in Carbon Dots for NIR-II Bioimaging.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Enhanced Solid-State Luminescence of Supramolecular Tessellation Assemblies Through Förster Resonance Energy Transfer From Counterions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Reversible iodine capture by nonporous adaptive hybrid[3]arene crystals.Chemical science · 2026Article
- Beyond Cocrystals: Hierarchical Functional Assemblies via Noncovalent Synthesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Supramolecular Phase Change Materials for Spatiotemporally Thermal Energy Utilization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Evaluation of Respirable Fraction by using Next Generation Impactor of Levosalbutamol Sulphate and Ipratropium bromide Metered Dose Inhaler.Current drug research reviews · 2026Article
- Nonporous Adaptive Crystals Based on Pillararene/Calixarene-Inspired Novel Macrocyclic Arenes.Exploration (Beijing, China) · 2025Review
- Machine Learning for Green Solvents: Assessment, Selection and Substitution.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Adsorptive Separation of Chlorobenzene and Chlorocyclohexane by Nonporous Adaptive Crystals of Perethylated Pillar[6]arene.Molecules (Basel, Switzerland) · 2025Article
- Hydrogen-bonded supramolecular polymer networks for effective removal of perchlorate in water via clustered hydrogen-bonding.Nature communications · 2025Article
- Applications of cell penetrating peptide-based drug delivery system in immunotherapy.Frontiers in immunology · 2025Review
- Calix[2]azolium[2]benzimidazolone hosts for selective binding of neutral substrates in water.Nature communications · 2024Article
- Lung Cancer Screening-Trends and Current Studies.Cancers · 2024Review
- Deep eutectic solvent self-assembled reverse nanomicelles for transdermal delivery of sparingly soluble drugs.Journal of nanobiotechnology · 2024Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
The combination of macrocyclic chemistry with co-crystal engineering has promoted the development of materials with vapochromic behaviors in supramolecular science. Herein, we develop a macrocycle co-crystal based on hybrid[4]arene and 1,2,4,5-tetracyanobenzene that is able to construct vapochromic materials. After the capture of benzene and toluene vapors, activated hybrid[4]arene-based co-crystal forms new structures, accompanied by color changes from brown to yellow. However, when hybrid[4]arene-based co-crystal captures cyclohexane and pyridine, neither structures nor colors change. Interestingly, hybrid[4]arene-based co-crystal can separate benzene from a benzene/cyclohexane equal-volume mixture and allow toluene to be removed from a toluene/ pyridine equal-volume mixture with purities reaching 100%. In addition, the process of adsorptive separation can be visually monitored. The selectivity of benzene from a benzene/cyclohexane equal-volume mixture and toluene from a toluene/ pyridine equal-volume mixture is attributed to the different changes in the charge-transfer interaction between hybrid[4]arene and 1,2,4,5-tetracyanobenzene when hybrid[4]arene-based co-crystal captures different vapors. Moreover, hybrid[4]arene-based co-crystal can be reused without losing selectivity and performance. This work constructs a vapochromic material for hydrocarbon separation.
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Registered trials
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