ReviewMolecules (Basel, Switzerland)2024
Atom-Precise Ligated Copper and Copper-Rich Nanoclusters with Mixed-Valent Cu(I)/Cu(0) Character: Structure-Electron Count Relationships.
Review in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Eight-electron Pt/Cu superatom encapsulating three "electron-donating" hydrides.Science advances · 2025Article
- Structural Transformation of Metastable Two-Electron Superatom Au-Doped Cu-Rich Alloy Nanocluster.Molecules (Basel, Switzerland) · 2024Article
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Authors and funding
2 authors.
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Abstract
Copper homometallic and copper-rich heterometallic nanoclusters with some Cu(0) character are reviewed. Their structure and stability are discussed in terms of their number of "free" electrons. In many aspects, this structural chemistry differs from that of their silver or copper homologs. Whereas the two-electron species are by far the most numerous, only one eight-electron species is known, but more electron-rich nanoclusters have also been reported. Owing to the relatively recent development of this chemistry, it is likely that more electron-rich species will be reported in the future.
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