Mono- and bis-Pd(ii) complexes of N-confused dithiahexaphyrin(1.1.1.1.1.0) with the absorption and aromaticity modulated by Pd(ii) coordination, macrocycle contraction and ancillary ligands.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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5 · Who and what money
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9 authors.
Meng SunKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.
Yongshu XieKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.ORCID https://orcid.org/0000-0001-8230-7599
Glib BaryshnikovDepartment of Science and Technology, Laboratory of Organic Electronics, Linköping University SE-601 74 Norrköping Sweden.ORCID https://orcid.org/0000-0002-0716-3385
Chengjie LiKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.ORCID https://orcid.org/0000-0001-5602-6566
Feng ShaKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.ORCID https://orcid.org/0000-0002-6780-8448
Xinyan WuKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.ORCID https://orcid.org/0000-0002-6942-7067
Hans ÅgrenDepartment of Physics and Astronomy, Uppsala University SE-751 20 Uppsala Sweden.
Shijun LiCollege of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University Hangzhou 311121 China.ORCID https://orcid.org/0000-0003-1480-9292
Qizhao LiKey Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology Shanghai 200237 China yshxie@ecust.edu.cn zhaolq@ecust.edu.cn.ORCID https://orcid.org/0000-0002-2046-7041
Funding
No grant is acknowledged in the PubMed record.
6 · The paper itself
Abstract
To further enrich the coordination chemistry of hexaphyrins and probe the underlying property-structural correlations, N-confused dithiahexaphyrin(1.1.1.1.1.0) (1) with 26 π-electron Hückel aromaticity was synthesized. Based on its unprecedented two unsymmetrical cavities, five palladium complexes 2, 3, 4-Ph, 4-Cl and 5 have been successfully synthesized under various coordinations. Thus, two mono-Pd(ii) complexes 2 and 3 with the Pd(ii) atom coordinated in the two different cavities were obtained by treating 1 with palladium reagents PdCl
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Mono- and bis-Pd(ii) complexes of N-confused dithiahexaphyrin(1.1.1.1.1.0) with the absorption and aromaticity modulated by Pd(ii) coordination, macrocycle contraction and ancillary ligands. · full record | OpenQuestion