Evidence map›Paper›PMID 38321026›Full record

ArticleNature communications2024

Ultra-stable and highly reactive colloidal gold nanoparticle catalysts protected using multi-dentate metal oxide nanoclusters.

Kang Xia, Takafumi Yatabe, Kentaro Yonesato, Soichi Kikkawa, Seiji Yamazoe, Ayako Nakata, Ryo Ishikawa, Naoya Shibata, Yuichi Ikuhara, Kazuya Yamaguchi and 1 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Bimetallic urchin-like Au@Pt/SiOMikrochimica acta · 2026
    Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Journal of the American Chemical Society · 2025
    Article
  12. Review
  13. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Kang XiaDepartment of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0002-9376-8953
Takafumi YatabeDepartment of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0001-5504-4762
Kentaro YonesatoDepartment of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.
Soichi KikkawaDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Tokyo, Japan.
Seiji YamazoeDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Tokyo, Japan.ORCID http://orcid.org/0000-0002-8382-8078
Ayako NakataResearch Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Ibaraki, Japan.ORCID http://orcid.org/0000-0002-3311-6283
Ryo IshikawaInstitute of Engineering Innovation, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0001-5801-0971
Naoya ShibataInstitute of Engineering Innovation, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0003-3548-5952
Yuichi IkuharaInstitute of Engineering Innovation, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0003-3886-005X
Kazuya YamaguchiDepartment of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0002-7661-4936
Kosuke SuzukiDepartment of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan. ksuzuki@appchem.t.u-tokyo.ac.jp.ORCID http://orcid.org/0000-0002-8123-1462

Funding

MEXT | Japan Science and Technology Agency (JST) JPMJFR2033MEXT | Japan Science and Technology Agency (JST) JPMJFR213MMEXT | Japan Society for the Promotion of Science (JSPS) KAKENHI 22H04971MEXT | JST | Precursory Research for Embryonic Science and Technology (PRESTO) JPMJPR18T7MEXT | JST | Precursory Research for Embryonic Science and Technology (PRESTO) JPMJPR19T9MEXT | JST | Precursory Research for Embryonic Science and Technology (PRESTO) JPMJPR20T4MEXT | JST | Precursory Research for Embryonic Science and Technology (PRESTO) JPMJPR227A
6 · The paper itself

Abstract

Owing to their remarkable properties, gold nanoparticles are applied in diverse fields, including catalysis, electronics, energy conversion and sensors. However, for catalytic applications of colloidal gold nanoparticles, the trade-off between their reactivity and stability is a significant concern. Here we report a universal approach for preparing stable and reactive colloidal small (~3 nm) gold nanoparticles by using multi-dentate polyoxometalates as protecting agents in non-polar solvents. These nanoparticles exhibit exceptional stability even under conditions of high concentration, long-term storage, heating and addition of bases. Moreover, they display excellent catalytic performance in various oxidation reactions of organic substrates using molecular oxygen as the sole oxidant. Our findings highlight the ability of inorganic multi-dentate ligands with structural stability and robust steric and electronic effects to confer stability and reactivity upon gold nanoparticles. This approach can be extended to prepare metal nanoparticles other than gold, enabling the design of novel nanomaterials with promising applications.

Identifiers

PMID38321026
PMCPMC10847421

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.