ArticleJournal of the American Chemical Society2024
Stepwise Operation of a Molecular Rotary Motor Driven by an Appel Reaction.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Article
- Kinetic Analysis of the Redox-Neutral Catalytic Mitsunobu Reaction: Dehydration, Kinetic Barriers, and Hopping between Potential Energy Surfaces.Journal of the American Chemical Society · 2025Article
- Unidirectional molecular rotary motor with remotely switchable rotation direction.Science advances · 2025Article
- Structural Influence of the Chemical Fueling System on a Catalysis-Driven Rotary Molecular Motor.Journal of the American Chemical Society · 2025Article
- Reversible Metal-Mediated Molecular Switching of a Phosphaethene Polyaromatic Hydrocarbon.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Bidirectional Molecular Motors by Controlling Threading and Dethreading Pathways of a Linked Rotaxane.Angewandte Chemie (International ed. in English) · 2025Article
- Divergent Synthesis of Chiroptical Molecular Switches Based on 1,2-Diaxial Atropisomers.JACS Au · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
To date, only a small number of chemistries and chemical fueling strategies have been successfully used to operate artificial molecular motors. Here, we report the 360° directionally biased rotation of phenyl groups about a C-C bond, driven by a stepwise Appel reaction sequence. The motor molecule consists of a biaryl-embedded phosphine oxide and phenol, in which full rotation around the biaryl bond is blocked by the P-O oxygen atom on the rotor being too bulky to pass the oxygen atom on the stator. Treatment with SOCl
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Registered trials
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