ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024
Incorporating Two Crown Ether Struts into the Backbone of Robust Zirconium-Based Metal-Organic Frameworks as Custom-Designed Efficient Collectors for Radioactive Metal Ions.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Conformationally Adaptive Crown Ether Embedded in a Metal Sulfide for Exceptional Strontium Capture.Angewandte Chemie (International ed. in English) · 2026Article
- Post-synthetically modified crown ether-based supramolecular framework for efficient radium sequestration.Nature communications · 2026Article
- Mesoporous Potassium-Based Metal-Organic Framework as a Drug Carrier.ACS central science · 2025Article
- A negatively-charged supramolecular trap for precisely catching strontium ion.Nature communications · 2025Article
- Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption.RSC advances · 2024Article
- Incorporating Two Crown Ether Struts into the Backbone of Robust Zirconium-Based Metal-Organic Frameworks as Custom-Designed Efficient Collectors for Radioactive Metal Ions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The incorporation of crown ether into metal-organic frameworks (MOFs) is garnered significant attention because these macrocyclic units can fine-tune the inherent properties of the frameworks. However, the synthesis of flexible crown ethers with precise structures as the fundamental building blocks of crystalline MOFs remains a challenging endeavor, with only a limited number of transition metal examples existing to date. Herein, 18-crown-6 and 24-crown-8 struts are successfully incorporated into the skeleton of zirconium-based MOFs to obtain two new and stable crown ether-based MOFs, denoted as ZJU-X100 and ZJU-X102. These newly developed MOFs displayed high porosity and remarkable stability when exposed to various solvents, boiling water, pH values, and even concentrated HCl conditions. Thanks to their highly ordered porous structure and high-density embedding of specific binding sites within tubular channels, these two MOFs exhibited extremely fast sorption kinetics and demonstrated outstanding performance in the uptake of strontium and cesium ions, respectively. Furthermore, the structures of Sr-adsorbed ZJU-X100 and Cs-adsorbed ZJU-X102 are solved and confirmed the precise location of Sr
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.