Evidence map›Paper›PMID 38303934›Full record

ArticleChemical science2024

Borylative transition metal-free couplings of vinyl iodides with various nucleophiles, alkenes or alkynes.

Gesa Seidler, Max Schwenzer, Florian Clausen, Constantin G Daniliuc, Armido Studer

Abstract read
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Gesa SeidlerOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster Corrensstraße 40 48149 Munster Germany studer@uni-muenster.de.ORCID https://orcid.org/0009-0000-3410-4025
Max SchwenzerOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster Corrensstraße 40 48149 Munster Germany studer@uni-muenster.de.ORCID https://orcid.org/0000-0002-5218-2120
Florian ClausenOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster Corrensstraße 40 48149 Munster Germany studer@uni-muenster.de.
Constantin G DaniliucOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster Corrensstraße 40 48149 Munster Germany studer@uni-muenster.de.ORCID https://orcid.org/0000-0002-6709-3673
Armido StuderOrganisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster Corrensstraße 40 48149 Munster Germany studer@uni-muenster.de.ORCID https://orcid.org/0000-0002-1706-513X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Alkyl boronic esters are highly valuable compounds in organic chemistry and related fields due to their good stability and highly versatile reactivity. In this edge article, stereoselective borylative couplings of vinyl iodides with various nucleophiles, alkenes or alkynes is reported. These coupling reactions proceed through stereospecific hydroboration and subsequent stereospecific 1,2-metallate rearrangement. The cascades utilize readily available reagents and proceed without the need of a transition metal catalyst.

Identifiers

PMID38303934
PMCPMC10829001

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.