ArticleNature chemistry2024
The synthesis and characterization of an iron(VII) nitrido complex.
Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer.Nature chemistry · 2026Article
- A Mononuclear Ruthenium(V)-Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N-Substituents From Alkenes in Water.Angewandte Chemie (International ed. in English) · 2026Article
- High-Valent Late Transition Metal-Oxo Complexes: Breaking Boundaries at the Oxo Wall and Beyond.Chemical reviews · 2026Review
- Isolation of a Terminal Cobalt Nitride in a Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- From 18- to 20-electron ferrocene derivatives via ligand coordination.Nature communications · 2025Article
- Praseodymium in the formal +5 oxidation state.Nature chemistry · 2025Article
- An Open-Shell FeJournal of the American Chemical Society · 2025Article
- Lifting iron higher and higher.Nature chemistry · 2024Article
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Authors and funding
11 authors.
Funding
Abstract
Complexes of iron in high oxidation states are captivating research subjects due to their pivotal role as active intermediates in numerous catalytic processes. Structural and spectroscopic studies of well-defined model complexes often provide evidence of these intermediates. In addition to the fundamental molecular and electronic structure insights gained by these complexes, their reactivity also affects our understanding of catalytic reaction mechanisms for small molecule and bond-activation chemistry. Here, we report the synthesis, structural and spectroscopic characterization of a stable, octahedral Fe(VI) nitrido complex and an authenticated, unique Fe(VII) species, prepared by one-electron oxidation. The super-oxidized Fe(VII) nitride rearranges to an Fe(V) imide through an intramolecular amination mechanism and ligand exchange, which is characterized spectroscopically and computationally. This enables combined reactivity and stability studies on a single molecular system of a rare high-valent complex redox pair. Quantum chemical calculations complement the spectroscopic parameters and provide evidence for a diamagnetic (S = 0) d
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