ArticleThe journal of physical chemistry letters2024
Collective Strong Coupling Modifies Aggregation and Solvation.
Article in The journal of physical chemistry letters, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Polaritonic Coupled Cluster Theory for Unpolarized Cavities Exploiting Point-Group Symmetry.Journal of chemical theory and computation · 2026Article
- Toward Reliable Spectroscopic Analysis of Reaction Kinetics in Polaritonic Chemistry.Nanophotonics (Berlin, Germany) · 2026Article
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Density-functional tight binding meets Maxwell: unraveling the mysteries of (strong) light-matter coupling efficiently.Nanophotonics (Berlin, Germany) · 2025Article
- Excited State Dynamics of COJournal of the American Chemical Society · 2025Article
- A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Electronic strong coupling modifies the ground-state intermolecular interactions in self-assembled chlorin molecules.Nature communications · 2025Article
- Molecular Polarizability under Vibrational Strong Coupling.Journal of chemical theory and computation · 2025Article
- Strong Coupling Quantum Electrodynamics Hartree-Fock Response Theory.The journal of physical chemistry. A · 2025Article
- Strong Coupling Møller-Plesset Perturbation Theory.Journal of chemical theory and computation · 2025Article
- Machine Learning for Polaritonic Chemistry: Accessing Chemical Kinetics.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Intermolecular (Coulombic) interactions are pivotal for aggregation, solvation, and crystallization. We demonstrate that the collective strong coupling of several molecules to a single optical mode results in notable changes in the molecular excitations around a single perturbed molecule, thus representing an impurity in an otherwise ordered system. A competition between short-range coulombic and long-range photonic correlations inverts the local transition density in a polaritonic state, suggesting notable changes in the polarizability of the solvation shell. Our results provide an alternative perspective on recent work in polaritonic chemistry and pave the way for the rigorous treatment of cooperative effects in aggregation, solvation, and crystallization.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.