ArticleNature materials2024
General room-temperature Suzuki-Miyaura polymerization for organic electronics.
Article in Nature materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
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- Base-Mediated Scalable Synthesis of Polybenzothiazoles: Fused-Heterocycle-Engineered Recovery of Precious Metals.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Open-flask, ambient temperature direct arylation synthesis of mixed ionic-electronic conductors.Science advances · 2025Article
- Contorted acene ribbons for stable and ultrasensitive neural probes.Science advances · 2025Article
- Quantum Batteries: A Materials Science Perspective.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Expedient Synthesis of Substituted Thieno[3,2-Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
- Erratum issued
Authors and funding
14 authors.
Funding
Abstract
π-Conjugated polymers (CPs) have broad applications in high-performance optoelectronics, energy storage, sensors and biomedicine. However, developing green and efficient methods to precisely synthesize alternating CP structures on a large scale remains challenging and critical for their industrialization. Here a room-temperature, scalable and homogeneous Suzuki-Miyaura-type polymerization reaction is developed with broad generality validated for 24 CPs including donor-donor, donor-acceptor and acceptor-acceptor connectivities, yielding device-quality polymers with high molecular masses. Furthermore, the polymerization protocol significantly reduces homocoupling structural defects, yielding more structurally regular and higher-performance electronic materials and optoelectronic devices than conventional thermally activated polymerizations. Experimental and theoretical studies reveal that a borate transmetalation process plays a key role in suppressing protodeboronation, which is critical for large-scale structural regularity. Thus, these results provide a general polymerization tool for the scalable production of device-quality CPs with alternating structural regularity.
Identifiers
38287128What OpenQuestion holds
Registered trials
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