ReviewPolymers2024
Thermodynamics of the Glassy Polymer State: Equilibrium and Non-Equilibrium Aspects.
Review in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
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Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This work examines, first, the non-equilibrium character of the glassy state of polymer systems and its significance in the development of novel materials for important technological applications. Subsequently, it summarizes the essentials of the generalized lattice fluid approach for the description of this highly complex non-equilibrium behavior with an approximate and simple, yet analytically powerful formalism. The working equations are derived in a straightforward and consistent manner by clearly defining the universal and specific variables needed to describe the discussed properties. The role of the non-random distribution of molecular species and free volume in the glassy system is also examined, as is the role of strong specific interactions, such as hydrogen-bonding networks. This work also reports examples of applications in a variety of representative systems, including glass densification, retrograde vitrification, increase in glass-transition temperature in hydrogen-bonded polymer mixtures, and hysteresis phenomena in sorption-desorption from glassy polymer matrices.
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