ArticleJournal of the American Chemical Society2024
On-Surface Synthesis of a Radical 2D Supramolecular Organic Framework.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Radical-Based On-Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes.Angewandte Chemie (International ed. in English) · 2026Article
- Designing Pancake-Bonded Heterodimers for Scanning Probe Microscopy.The journal of physical chemistry. A · 2026Article
- Light-Driven On-Surface Synthesis: Mechanisms, Strategies, and Architectures.Nanomaterials (Basel, Switzerland) · 2026Review
- Methylation-Induced Permanent Charge Polarization in Covalent Organic Frameworks for Visible Light-Driven Water Decontamination and Disinfection.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Locally induced Stark shifts of collective excitonic modes in polyradical aggregates.Beilstein journal of nanotechnology · 2026Article
- A Review of On-Surface Synthesis and Characterization of Macrocycles.Nanomaterials (Basel, Switzerland) · 2025Review
- On-Surface Synthesis of a Large-Scale 2D MOF with Competing π-d Ferromagnetic/Antiferromagnetic Order.Journal of the American Chemical Society · 2025Article
- Monitoring On-Surface Chemical Reactions by Low-Energy Electron Microscopy: from Conformation Change to Ring Closure in 2D Molecular Gas.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Planar and Curved π-Extended Porphyrins by On-Surface Cyclodehydrogenation.Journal of the American Chemical Society · 2024Article
- Beyond Spin Models in Orbitally Degenerate Open-Shell Nanographenes.Nano letters · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The design of supramolecular organic radical cages and frameworks is one of the main challenges in supramolecular chemistry. Their interesting material properties and wide applications make them very promising for (photo)redox catalysis, sensors, or host-guest spin-spin interactions. However, the high reactivity of radical organic systems makes the design of such supramolecular radical assemblies challenging. Here, we report the on-surface synthesis of a purely organic supramolecular radical framework on Au(111), by combining supramolecular and on-surface chemistry. We employ a tripodal precursor, functionalized with 7-azaindole groups that, catalyzed by a single gold atom on the surface, forms a radical molecular product constituted by a π-extended fluoradene-based radical core. The radical products self-assemble through hydrogen bonding, leading to extended 2D domains ordered in a Kagome-honeycomb lattice. This approach demonstrates the potential of on-surface synthesis for developing 2D supramolecular radical organic chemistry.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.