ReviewACS catalysis2024
Exploiting Multimetallic Cooperativity in the Ring-Opening Polymerization of Cyclic Esters and Ethers.
Review in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
11 citing papers in PubMed.
- Article
- Article
- Recent Advances in the Stereoselective Polymerization of Epoxides and Applications of Stereocontrolled Polyethers.ChemPlusChem · 2026Review
- Highly Stable Heterometallic Catalysts for Polyester Depolymerization and Polymerization at High Temperatures.Journal of the American Chemical Society · 2025Article
- Robust, Thermally Stable and Impurity-Tolerant Aluminum-Based Catalyst System for Polylactide Production under Industrial Conditions.Polymer science & technology (Washington, D.C.) · 2025Article
- General, Quantified Structure-Performance Correlations for Synergistic Heteronuclear Electro‑, Polymerization, and Asymmetric Catalysts.ACS catalysis · 2025Review
- The Effect of Alkyl Substituents on the Formation and Structure of Homochiral (Molecules (Basel, Switzerland) · 2025Article
- Article
- Simple divalent metal salts as robust and efficient initiators for the ring-opening polymerisation ofRSC advances · 2024Article
- Ti and Zr complexes bearing guanidine-phenolate ligands: coordination chemistry and polymerization studies.RSC advances · 2024Article
- Review
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The use of multimetallic complexes is a rapidly advancing route to enhance catalyst performance in the ring-opening polymerization of cyclic esters and ethers. Multimetallic catalysts often outperform their monometallic analogues in terms of reactivity and/or polymerization control, and these improvements are typically attributed to "multimetallic cooperativity". Yet the origins of multimetallic cooperativity often remain unclear. This review explores the key factors underpinning multimetallic cooperativity, including metal-metal distances, the flexibility, electronics and conformation of the ligand framework, and the coordination environment of the metal centers. Emerging trends are discussed to provide insights into why cooperativity occurs and how to harness cooperativity for the development of highly efficient multimetallic catalysts.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.