Evidence map›Paper›PMID 38235652›Full record

ArticleThe Journal of organic chemistry2024

Anomeric Triflates versus Dioxanium Ions: Different Product-Forming Intermediates from 3-Acyl Benzylidene Mannosyl and Glucosyl Donors.

Wouter A Remmerswaal, Hidde Elferink, Kas J Houthuijs, Thomas Hansen, Floor Ter Braak, Giel Berden, Stefan van der Vorm, Jonathan Martens, Jos Oomens, Gijsbert A van der Marel and 2 more

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Stereoselectivity of Galactosylation Reactions In Vacuo.Journal of the American Chemical Society · 2026
    Article
  2. Mechanism of 3-The Journal of organic chemistry · 2025
    Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. ZnIMolecules (Basel, Switzerland) · 2024
    Review
  8. Article
  9. Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Wouter A RemmerswaalLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2300 RA, The Netherlands.ORCID 0000-0002-1040-4311
Hidde ElferinkInstitute for Molecules and Materials, Radboud University, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.
Kas J HouthuijsInstitute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, Nijmegen 6525 ED, The Netherlands.
Thomas HansenLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2300 RA, The Netherlands.ORCID 0000-0002-6291-1569
Floor Ter BraakInstitute for Molecules and Materials, Radboud University, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.
Giel BerdenInstitute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, Nijmegen 6525 ED, The Netherlands.ORCID 0000-0003-1500-922X
Stefan van der VormLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2300 RA, The Netherlands.ORCID 0000-0002-4047-9373
Jonathan MartensInstitute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, Nijmegen 6525 ED, The Netherlands.ORCID 0000-0001-9537-4117
Jos OomensInstitute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, Nijmegen 6525 ED, The Netherlands.ORCID 0000-0002-2717-1278
Gijsbert A van der MarelLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2300 RA, The Netherlands.
Thomas J BoltjeInstitute for Molecules and Materials, Radboud University, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.
Jeroen D C CodéeLeiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2300 RA, The Netherlands.ORCID 0000-0003-3531-2138

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Minimal structural differences in the structure of glycosyl donors can have a tremendous impact on their reactivity and the stereochemical outcome of their glycosylation reactions. Here, we used a combination of systematic glycosylation reactions, the characterization of potential reactive intermediates, and in-depth computational studies to study the disparate behavior of glycosylation systems involving benzylidene glucosyl and mannosyl donors. While these systems have been studied extensively, no satisfactory explanations are available for the differences observed between the 3-

Identifiers

PMID38235652
PMCPMC10845153

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.