ArticleProceedings of the National Academy of Sciences of the United States of America2024
Interfacial solvation-structure regulation for stable Li metal anode by a desolvation coating technique.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Solvent polarizability governs Li⁺ transport kinetics for high energy lithium metal batteries.Nature communications · 2026Article
- Dynamic Ion-Adsorption Interface for Uniform Lithium-Ion Transport in High-Performance Lithium Metal Batteries.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Ultra-Uniform Lithium-Ion Transport Enabled by Supramolecular Polymeric Networks as Artificial Solid Electrolyte Interphase Layers for Highly Stable Lithium-Ion Battery Anodes.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Substrate Designs for Stable Potassium Metal Anodes.ACS applied energy materials · 2025Review
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Authors and funding
15 authors.
Funding
Abstract
Rechargeable lithium (Li) metal batteries face challenges in achieving stable cycling due to the instability of the solid electrolyte interphase (SEI). The Li-ion solvation structure and its desolvation process are crucial for the formation of a stable SEI on Li metal anodes and improving Li plating/stripping kinetics. This research introduces an interfacial desolvation coating technique to actively modulate the Li-ion solvation structure at the Li metal interface and regulate the participation of the electrolyte solvent in SEI formation. Through experimental investigations conducted using a carbonate electrolyte with limited compatibility to Li metal, the optimized desolvation coating layer, composed of 12-crown-4 ether-modified silica materials, selectively displaces strongly coordinating solvents while simultaneously enriching weakly coordinating fluorinated solvents at the Li metal/electrolyte interface. This selective desolvation and enrichment effect reduce solvent participation to SEI and thus facilitate the formation of a LiF-dominant SEI with greatly reduced organic species on the Li metal surface, as conclusively verified through various characterization techniques including XPS, quantitative NMR, operando NMR, cryo-TEM, EELS, and EDS. The interfacial desolvation coating technique enables excellent rate cycling stability (i.e., 1C) of the Li metal anode and prolonged cycling life of the Li||LiCoO
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