ArticleJournal of the American Chemical Society2024
Light-Driven Purification of Progesterone from Steroid Mixtures Using a Photoresponsive Metal-Organic Capsule.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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Who cites it
10 citing papers in PubMed, 36 citations in OpenAlex.
- Oxidative PCET-Triggered Benzylic C─H Iminolactonization via 1,5-HAT/Cyclization Enabled by Cage-Confined Photocatalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Decoding the Principles Governing Molecular Cage Precipitation of Aliphatic and Perfluoroalkyl Acids (PFAAs).ACS applied materials & interfaces · 2026Article
- Toward Sustainable Testosterone Manufacturing: Green Chemistry and Microbial Biotransformation Approaches.International journal of molecular sciences · 2026Review
- From the same supramolecular framework to distinct types of porous liquids via in-situ transformation.Nature communications · 2026Article
- Light-Controlled Functions with Metal-Organic Capsules: From Guest Release to Catalysis, Separation, and Molecular Transport.Accounts of chemical research · 2026Article
- Light them up: photoresponsive imine-containing systems.Chemical science · 2025Review
- Coordination sphere interactions drive isomer selection in heteroleptic Pd(ii) cages with low-symmetry ligands.Chemical science · 2025Article
- Light-Driven Lithium Extraction from Mixtures of Alkali Cations Using an Azobipyridine Ligand.Journal of the American Chemical Society · 2025Article
- Synthesis, Characterization, and Photochemistry of a GaInorganic chemistry · 2024Article
- Engineering a Surfactant Trap via Postassembly Modification of an Imine Cage.Chemistry of materials : a publication of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chemical separations are expensive, consuming 10-15% of humanity's global energy budget. Many current separation methods employ thermal energy for distillation, often through the combustion of carbon-containing fuels, or extractions and crystallizations from organic solvents, which must then be discarded or redistilled, with a substantial energetic cost. The direct use of renewable energy sources, such as light, could enable the development of novel separations processes, as is required for the transition away from fossil fuel use. Metal-organic capsules, which can selectively bind molecules from mixtures, can provide the foundation for these novel separations processes. Here we report a tetrahedral metal-organic capsule bearing light-responsive diazo moieties around its metal-ion vertices. This capsule can be used to selectively separate progesterone from a mixture of steroids in a process driven by visible light energy. Our process combines biphasic extraction and selective binding of progesterone with the light-driven release of this molecule in purified form. Ultimately, our process might be adapted to the purifications of the many other fine chemical products that are bound selectively by capsules.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.