Evidence map›Paper›PMID 38230364›Full record

ArticleACS applied polymer materials2024

Solubilizing Benzodifuranone-Based Conjugated Copolymers with Single-Oxygen-Containing Branched Side Chains.

Diego R Hinojosa, Nathan J Pataki, Pietro Rossi, Andreas Erhardt, Shubhradip Guchait, Francesca Pallini, Christopher McNeill, Christian Müller, Mario Caironi, Michael Sommer

Abstract read
In one paragraph

Article in ACS applied polymer materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Diego R HinojosaInstitut für Chemie, Technische Universität Chemnitz, Straße der Nationen 62, 09111 Chemnitz, Germany.ORCID https://orcid.org/0000-0002-4849-2062
Nathan J PatakiCenter for Nano Science and Technology, Via Rubattino 81, 20134 Milano, Italy.ORCID https://orcid.org/0000-0002-3691-5427
Pietro RossiCenter for Nano Science and Technology, Via Rubattino 81, 20134 Milano, Italy.
Andreas ErhardtDepartment of Materials Science and Engineering, Monash University, Clayton, Victoria 3800, Australia.
Shubhradip GuchaitInstitute Charles Sadron, Université de Strasbourg, Strasbourg F-67000, France.
Francesca PalliniDepartment of Materials Science, Università di Milano-Bicocca, via Cozzi 55, 20125 Milan, Italy.
Christopher McNeillDepartment of Materials Science and Engineering, Monash University, Clayton, Victoria 3800, Australia.ORCID https://orcid.org/0000-0001-5221-878X
Christian MüllerDepartment of Chemistry and Chemical Engineering Chalmers University of Technology Göteborg 412 96, Sweden.ORCID https://orcid.org/0000-0001-7859-7909
Mario CaironiCenter for Nano Science and Technology, Via Rubattino 81, 20134 Milano, Italy.ORCID https://orcid.org/0000-0002-0442-4439
Michael SommerInstitut für Chemie, Technische Universität Chemnitz, Straße der Nationen 62, 09111 Chemnitz, Germany.ORCID https://orcid.org/0000-0002-2377-5998

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Single-oxygen-containing branched side chains are designed and used to solubilize n-type copolymers consisting of BDF (benzodifuranone), isatin, and thiophene-based units. We present a simple synthetic approach to side chains with varying linker distances between the backbone and the branching point. The synthetic pathway is straightforward and modular and starts with commercially available reagents. The side chains give rise to excellent solubilities of BDF-thiophene copolymers of up to 90 mg/mL, while still being moderate in size (26-34 atoms large). The excellent solubility furthermore allows high molar mass materials. BDF-thiophene copolymers are characterized in terms of optoelectronic and thermoelectric properties. The electrical conductivity of chemically doped polymers is found to scale with molar mass, reaching ∼1 S/cm for the highest molar mass and longest backbone-branching point distance.

Identifiers

PMID38230364
PMCPMC10788869

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.